Reactions of N-heterocyclic carbene-based chalcogenoureas with halogens: a diverse range of outcomes

Author:

Saab Marina1,Nelson David J.2ORCID,Leech Matthew C.3ORCID,Lam Kevin3ORCID,Nolan Steven P.4ORCID,Nahra Fady15ORCID,Van Hecke Kristof1ORCID

Affiliation:

1. XStruct, Department of Chemistry, Ghent University, Krijgslaan 281, Building S3, 9000 Ghent, Belgium

2. WestCHEM Department of Pure & Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, Scotland, UK

3. School of Science, University of Greenwich, Chatham Maritime ME4 4TB, UK

4. Department of Chemistry, Ghent University, Krijgslaan 281, Building S3, 9000 Ghent, Belgium

5. VITO (Flemish Institute for Technological Research), Boeretang 200, 2400 Mol, Belgium

Abstract

The reactions of chalcogenoureas derived from N-heterocyclic carbenes, with halogens are investigated. These lead to a diverse range of adducts. This information was used to extrapolate a structure/activity relationship and to explain the observed trends.

Funder

Fonds Wetenschappelijk Onderzoek

Bijzonder Onderzoeksfonds

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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