Synthesis and hydrolysis of gas-phase lanthanide and actinide oxide nitrate complexes: a correspondence to trivalent metal ion redox potentials and ionization energies-Reference-Cited by-同舟云学术

Synthesis and hydrolysis of gas-phase lanthanide and actinide oxide nitrate complexes: a correspondence to trivalent metal ion redox potentials and ionization energies

Published:2015 Issue:15 Volume:17 Page:9942-9950
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lucena Ana F.¹²³⁴⁵,Lourenço Célia¹²³⁴⁵,Michelini Maria C.⁶⁷⁸⁹,Rutkowski Philip X.¹⁰¹¹¹²¹³,Carretas José M.¹²³⁴⁵,Zorz Nicole¹⁴¹⁵¹⁶¹⁷¹⁸,Berthon Laurence¹⁴¹⁵¹⁶¹⁷¹⁸,Dias Ana¹⁹²³²⁰⁵,Conceição Oliveira M.¹⁹²³²⁰⁵,Gibson John K.¹⁰¹¹¹²¹³,Marçalo Joaquim¹²³⁴⁵

Affiliation:

1. Centro de Ciências e Tecnologias Nucleares

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 2695-066 Bobadela LRS

5. Portugal

6. Dipartimento di Chimica

7. Università della Calabria

8. 87030 Arcavacata di Rende

9. Italy

10. Chemical Sciences Division

11. Lawrence Berkeley National Laboratory

12. Berkeley

13. USA

14. CEA

15. Nuclear Energy Division

16. Radiochemistry and Processes Department

17. Laboratory of Ligands-Actinides Interactions

18. 30207 Bagnols-sur-Cèze

19. Centro de Química Estrutural

20. 1049-001 Lisboa

Abstract

Gas-phase hydrolysis of lanthanide/actinide MO₃(NO₃)₃⁻ions relates to the stabilities of the M^IVoxidation states, which correlate with IV/III solution reduction potentials and 4th ionization energies.

Funder

Office of Science

European Commission

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP00515A

Reference54 articles.

1. NIST Chemistry WebBook, NIST Standard Reference Database Number 69, ed. P. J. Linstrom and W. G. Mallard, National Institute of Standards and Technology, Gaithersburg, MD, 2014

2. The thermal properties of inorganic compounds

3. Thermal decomposition of metal nitrates and their hydrates

4. Nickel-cobalt oxide spinels prepared by thermal decomposition of nickel(II)-cobalt(II) hydroxide nitrates

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