Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state-Reference-Cited by-同舟云学术

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state

Published:2024 Issue:18 Volume:15 Page:6874-6883
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tricoire Maxime¹,Hsueh Fang-Che¹^ORCID,Keener Megan¹^ORCID,Rajeshkumar Thayalan²,Scopelliti Rosario³^ORCID,Zivkovic Ivica⁴,Maron Laurent²^ORCID,Mazzanti Marinella¹^ORCID

Affiliation:

1. Group of Coordiantion Chemistry, Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland

2. Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, Cedex 4, 31077 Toulouse, France

3. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland

4. Laboratory for Quantum Magnetism, Institute of Physics, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland

Abstract

Robust arene-anchored polydentate siloxide ligands allow to control unwanted ligand rearrangements for the isolation of Tb(iv) complexes thus enabling the use of the Tb(iii)/Tb(iv) couple for the separation of Tb from the neighboring Dy ion.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

École Polytechnique Fédérale de Lausanne

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00051J

Reference61 articles.

1. Siloxide Podand Ligand as a Scaffold for Molybdenum-Catalyzed Alkyne Metathesis and Isolation of a Dynamic Metallatetrahedrane Intermediate

2. “Canopy Catalysts” for Alkyne Metathesis: Molybdenum Alkylidyne Complexes with a Tripodal Ligand Framework

3. The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis

4. The difficult search for organocerium(iv) compounds

5. Recent advances in the coordination chemistry of cerium(IV) complexes

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