Enhanced electronic communication through a conjugated bridge in a porphyrin–fullerene donor

Enhanced electronic communication through a conjugated bridge in a porphyrin–fullerene donor–acceptor couple

Published:2021 Issue:33 Volume:9 Page:10889-10898
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Caballero Rubén¹^ORCID,Calbo Joaquín²^ORCID,Aragó Juan²^ORCID,de la Cruz Pilar¹^ORCID,Ortí Enrique²^ORCID,Tkachenko Nikolai V.³^ORCID,Langa Fernando¹^ORCID

Affiliation:

1. Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), Universidad de Castilla-La Mancha, Campus de la Fábrica de Armas, 45071 Toledo, Spain

2. Instituto de Ciencia Molecular, Universidad de Valencia, 46950 Paterna, Spain

3. Faculty of Engineering and Natural Science, Tampere University, P. O. Box 541, Tampere 33101, Finland

Abstract

The electronic communication between the terminal electron-donor ZnP and electron-acceptor C60 units is enhanced by the conjugated EDOTV-based spacer leading to photoinduced electron transfer over the distance >2 nm in the picosecond time domain.

Funder

Junta de Comunidades de Castilla-La Mancha

Ministerio de Ciencia e Innovación

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TC/D1TC01160J

Reference32 articles.

1. R. E.Blankenship , Molecular Mechanisms of Photosynthesis , Wiley-Blackwell , Chichester , 2001