Donor–acceptor interactions of gold(iii) porphyrins with cobalt(ii) phthalocyanine: chemical structure of products, their spectral characterization and DFT study

Author:

Bichan Nataliya1ORCID,Tsaturyan Arshak23ORCID,Ovchenkova Ekaterina1ORCID,Kudryakova Nadezhda1ORCID,Gostev Fedor4,Shelaev Ivan4,Aybush Arseny4,Nadtochenko Victor45ORCID,Lomova Tatyana1ORCID

Affiliation:

1. G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo, Russia

2. Univ Lyon, UJM-Saint-Etienne, CNRS, IOGS, Laboratoire Hubert Curien UMR5516, F-42023 St-Etienne, France

3. Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

4. N.N. Semenov Institute of Chemical Physics of the Russian Academy of Sciences, Moscow, Russia

5. Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia

Abstract

The axial bonding of cobalt(ii) phthalocyanine with gold(iii) porphyrins, the structure, the spectral/electrochemical properties of the resulting donor–acceptor complexes and photoinduced electron transfer in them are studied.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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