Selective Si–C(sp<sup>3</sup>) bond cleavage of a silyl-bridged amido alkyl ligand in an yttrium complex-Reference-Cited by-同舟云学术

Selective Si–C(sp³) bond cleavage of a silyl-bridged amido alkyl ligand in an yttrium complex

Published:2023 Issue:12 Volume:52 Page:3807-3814
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cai Jiamin¹,Zhang Jie¹^ORCID,Zhou Xigeng¹^ORCID

Affiliation:

1. Department of Chemistry, Fudan University, No. 2005, Songhu Road, Shanghai 200438, China

Abstract

Rare-earth-mediated selective endocyclic and exocyclic Si–C(sp3) bond cleavage of a silyl-modified silylamido ligand was realized through the nucleophilic addition of unsaturated molecules such as CO, CS2, and organonitriles.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00149K

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