Selective Si–C(sp3) bond cleavage of a silyl-bridged amido alkyl ligand in an yttrium complex

Author:

Cai Jiamin1,Zhang Jie1ORCID,Zhou Xigeng1ORCID

Affiliation:

1. Department of Chemistry, Fudan University, No. 2005, Songhu Road, Shanghai 200438, China

Abstract

Rare-earth-mediated selective endocyclic and exocyclic Si–C(sp3) bond cleavage of a silyl-modified silylamido ligand was realized through the nucleophilic addition of unsaturated molecules such as CO, CS2, and organonitriles.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference64 articles.

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4. R. G.Jones , W.Ando and J.Chojnowski , Silicon-containing polymers: the science and technology of their synthesis and applications , Springer Science & Business Media , 2013

5. Gold-Catalyzed Direct Arylation

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