Selective 1,2-insertion of carbodiimides and substrate-divergent silyl group migration at 1-metallacyclobuta-2,3-dienes-Reference-Cited by-同舟云学术

Selective 1,2-insertion of carbodiimides and substrate-divergent silyl group migration at 1-metallacyclobuta-2,3-dienes

Published:2023 Issue:12 Volume:10 Page:3584-3594
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Shi Xinzhe¹²^ORCID,Li Sihan²,Spannenberg Anke²,Reiß Fabian²^ORCID,Beweries Torsten²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, P. R. China

2. Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany

Abstract

Carbodiimides undergo 1,2-insertion into 1-metalllacyclobuta-2,3-diene complexes, followed by silyl group migration, the nature of which depends on the carbodiimide substrate.

Funder

Deutsche Forschungsgemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI00449J

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