Supramolecular [Na(15-crown-5)]+ cations anchored to face-sharing octahedral lead bromide chains featuring a rotor-like one-dimensional perovskite with a reversible isostructural phase transition near room temperature-Reference-Cited by-同舟云学术

Supramolecular [Na(15-crown-5)]+ cations anchored to face-sharing octahedral lead bromide chains featuring a rotor-like one-dimensional perovskite with a reversible isostructural phase transition near room temperature

Published:2021 Issue:44 Volume:23 Page:7787-7793
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Yuan Guo-Jun¹^ORCID,Zhou Hong¹,Li Li¹,Chen Hong¹,Ren Xiao-Ming²

Affiliation:

1. Key Laboratory of Advanced Functional Materials of Nanjing, Department of Chemistry, Nanjing Xiaozhuang University, Nanjing 211171, P. R. China

2. State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular of Engineering, Nanjing Tech University, Nanjing 211816, P. R. China

Abstract

A 1D rotor-like organic perovskite, {[Na(15-crown-5)]PbBr3}n, features a high-κ nature and experiences a reversible isostructural phase transition near room temperature.

Funder

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CE/D1CE01273H

Reference49 articles.

1. Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells

2. A Review on Organic–Inorganic Halide Perovskite Photodetectors: Device Engineering and Fundamental Physics