Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells

Author:

Yang Woon Seok1,Park Byung-Wook1,Jung Eui Hyuk2ORCID,Jeon Nam Joong2,Kim Young Chan2,Lee Dong Uk3ORCID,Shin Seong Sik2ORCID,Seo Jangwon2,Kim Eun Kyu4ORCID,Noh Jun Hong25ORCID,Seok Sang Il12ORCID

Affiliation:

1. Perovtronics Research Center, School of Natural Science, and School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology, 50 UNIST-gil, Eonyang-eup, Ulju-gun, Ulsan 44919, Korea.

2. Division of Advanced Materials, Korea Research Institute of Chemical Technology, 141 Gajeong-Ro, Yuseong-Gu, Daejeon 34114, Korea.

3. NAND Product Engineering Group, SK Hynix Inc., Icheon 17336, Korea.

4. Department of Physics and Quantum Function Research Laboratory, Hanyang University, Seoul 04763, Korea.

5. School of Civil, Environmental and Architectural Engineering, Korea University, Seoul 136-713, Republic of Korea.

Abstract

Healing defects with triiodide ions Deep-level defects in organic-inorganic perovskites decrease the performance of solar cells through unproductive recombination of charge carriers. Yang et al. show that introducing additional triiodide ions during the formation of layers of formamidinium lead iodide, which also contain small amounts of methylammonium lead bromide, suppresses the formation of deep-level defects. This process boosts the certified efficiency of 1-cm 2 solar cells to almost 20%. Science , this issue p. 1376

Funder

Global Frontier R&D (Research and Development) Program of the Center for Multiscale Energy System

Climate Change Program

National Research Foundation of Korea

Basic Science Research Program

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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