Catalyst carbonylation: a hidden, but essential, step in reaction initiation
Author:
Affiliation:
1. Loker Hydrocarbon Research Institute and Department of Chemistry
2. University of Southern California
3. Los Angeles
4. USA
Abstract
This minireview documents cases where catalyst carbonylation can be detrimental, beneficial, or even essential in the activation and lifecycle of catalysis for hydrogen transfer reactions.
Funder
National Science Foundation
U.S. Department of Energy
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00322D
Reference35 articles.
1. 100 years of metal carbonyls: a serendipitous chemical discovery of major scientific and industrial impact
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3. The Milstein Bipyridyl PNN Pincer Complex of Ruthenium Becomes a Noyori-Type Catalyst under Reducing Conditions
4. Organic syntheses by means of noble metal compounds XXI. Decarbonylation of aldehydes using rhodium complex
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