Pressurized formic acid dehydrogenation: an entropic spring replaces hydrogen compression cost-Reference-Cited by-同舟云学术

Pressurized formic acid dehydrogenation: an entropic spring replaces hydrogen compression cost

Published:2022 Issue:23 Volume:12 Page:7182-7189
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Do Van K.¹^ORCID,Alfonso Vargas Nicolas¹^ORCID,Chavez Anthony J.¹^ORCID,Zhang Long¹,Cherepakhin Valeriy¹^ORCID,Lu Zhiyao¹,Currier Robert P.²,Dub Pavel A.²^ORCID,Gordon John C.³,Williams Travis J.¹^ORCID

Affiliation:

1. Loker Hydrocarbon Research Institute, Wrigley Institute for Environmental Studies, and, Department of Chemistry, University of Southern California, Los Angeles, California, 90089, USA

2. Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

3. National Security Education Center (NSEC), Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

Abstract

Several catalysts are shown to evolve useful H2 pressure from formic acid dehydrogenation, to replace compression cost with reaction entropy. Many of them rely on trace CO to initiate effectively. Mechanistic rationale and applications are discussed.

Funder

U.S. Department of Energy

National Institutes of Health

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY00676F

Reference43 articles.

1. Hydrogen Technologies R&D Overview, (Hydrogen program, accessed June 30, 2021 ), https://www.hydrogen.energy.gov/pdfs/review21/plenary7_stetson_2021_o.pdf

2. Hydrogen as an energy carrier: Prospects and challenges

3. Towards a Practical Setup for Hydrogen Production from Formic Acid

4. Ligand Effect on the Stability of Water‐Soluble Iridium Catalysts for High‐Pressure Hydrogen Gas Production by Dehydrogenation of Formic Acid

5. Catalyst carbonylation: a hidden, but essential, step in reaction initiation

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Roles of Solvent in the Catalytic Hydrogen Release from Liquid Organic Hydrogen Carriers: Chemical, Thermodynamical and Technological Aspects;Topics in Catalysis;2024-05-20

2. An immobilized (carbene)nickel catalyst for water oxidation;Polyhedron;2024-04

3. Sequential reactions toward a high-pressure H2 generation from a mixture of sodium borohydride and formic acid;Cell Reports Physical Science;2024-01

4. Recycling organoiridium waste to [(1,5-cyclooctadiene)IrCl]₂;Green Chemistry;2024

5. An ambient pressure, direct hydrogenation of ketones;Chemical Communications;2023