(2-Ketulosonyl)onate 2,3-O-thionocarbonate donors for the synthesis of KO and KDO α-glycosides and a one-pot glycosylation method for 2-keto acid donors
Author:
Affiliation:
1. Applied Chemistry Department
2. National Chiao Tung University
3. 1001
4. University Road
5. Hsinchu City
Abstract
Bifunctional (2-ketulosonyl)onate thionocarbonates are effective donors for the synthesis of KO and KDO α-glycosides with perfect control in stereoselectivity.
Funder
Ministry of Science and Technology, Taiwan
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00630K
Reference53 articles.
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3. Sinorhizobium meliloti strain 1021 produces a low-molecular-mass capsular polysaccharide that is a homopolymer of 3-deoxy-D-manno-oct-2-ulosonic acid harboring a phospholipid anchor
4. Lipopolysaccharide: Biosynthetic pathway and structure modification
5. The sugar 3-deoxy-d-manno-oct-2-ulosonic acid (Kdo) as a characteristic component of bacterial endotoxin — a review of its biosynthesis, function, and placement in the lipopolysaccharide core
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