(2-Ketulosonyl)onate 2,3-O-thionocarbonate donors for the synthesis of KO and KDO α-glycosides and a one-pot glycosylation method for 2-keto acid donors-Reference-Cited by-同舟云学术

(2-Ketulosonyl)onate 2,3-O-thionocarbonate donors for the synthesis of KO and KDO α-glycosides and a one-pot glycosylation method for 2-keto acid donors

Published:2020 Issue:16 Volume:7 Page:2179-2186
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Mong Kwok-Kong Tony¹²³⁴⁵^ORCID,Pradhan Tapan Kumar¹²³⁴⁵,Chiu Cheng-Hsin¹²³⁴⁵,Hung Wei-Cheng¹²³⁴⁵,Chen Chao-Ju¹²³⁴⁵,Wang Yi-Fang¹²³⁴⁵

Affiliation:

1. Applied Chemistry Department

2. National Chiao Tung University

3. 1001

4. University Road

5. Hsinchu City

Abstract

Bifunctional (2-ketulosonyl)onate thionocarbonates are effective donors for the synthesis of KO and KDO α-glycosides with perfect control in stereoselectivity.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00630K

Reference53 articles.

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2. O. Holst , Structure of the Lipopolysaccharide Core Region , In Bacterial Lipopolysaccharides , ed. Y. A. Knirel and M. A. Valvano , Springer Vienna , Wien , 2011 , pp. 21–39

3. Sinorhizobium meliloti strain 1021 produces a low-molecular-mass capsular polysaccharide that is a homopolymer of 3-deoxy-D-manno-oct-2-ulosonic acid harboring a phospholipid anchor

4. Lipopolysaccharide: Biosynthetic pathway and structure modification

5. The sugar 3-deoxy-d-manno-oct-2-ulosonic acid (Kdo) as a characteristic component of bacterial endotoxin — a review of its biosynthesis, function, and placement in the lipopolysaccharide core

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