Multi-nuclear NMR of axially chiral biaryls in polypeptide orienting solvents: spectral discriminations and enantiorecognition mechanisms

Author:

Berdagué Philippe12345,Herbert-Pucheta Jose-Enrique12345,Jha Vishwajeet678910,Panossian Armen678910,Leroux Frédéric R.678910ORCID,Lesot Philippe12345

Affiliation:

1. Laboratoire de RMN en Milieu Orienté

2. Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO)

3. UMR CNRS 8182

4. Université Paris-Sud

5. Université Paris-Saclay

6. Laboratoire de Chimie Moléculaire

7. Université de Strasbourg

8. UMR CNRS 7509

9. ECPM

10. 67087 Strasbourg

Abstract

The analytical potential of multinuclear NMR using chiral liquid crystals to discriminate between enantiomers of axially chiral biaryls is explored.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference90 articles.

1. G. Bringmann , G.Günther, M.Ochse, O.Schupp and S.Tasler, in Progress in the Chemistry of Organic Natural Products, ed. W. Herz, H. Falk, G. W. Kirby, R. E. Moore and C. Tamm, Springer, New York, 2001, vol. 82, p. 1

2. Studies directed toward the synthesis of vancomycin and related cyclic peptides

3. Chemistry, Biology, and Medicine of the Glycopeptide Antibiotics

4. O. Baudoin and F.Guéritte, in Studies in Natural Product Chemistry, ed. Atta-Ur-Rahman, Elsevier, 2003, vol. 29, p. 355

5. Construction of the biaryl-part of vancomycin aglycon via atropo-diastereoselective Suzuki–Miyaura coupling

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