β-Trioxopyrrocorphins: pyrrocorphins of graded aromaticity-Reference-Cited by-同舟云学术

β-Trioxopyrrocorphins: pyrrocorphins of graded aromaticity

Published:2021 Issue:37 Volume:12 Page:12292-12301
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chaudhri Nivedita¹^ORCID,Guberman-Pfeffer Matthew J.¹^ORCID,Li Ruoshi¹,Zeller Matthias²^ORCID,Brückner Christian¹^ORCID

Affiliation:

1. Department of Chemistry, University of Connecticut, Storrs, CT 06269-3060, USA

2. Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907-2084, USA

Abstract

The four possible pyrrocorphin isomers were prepared. Remarkably, they show regiochemically dependent aromaticity attributed to the presence of a 16-membered, 18 π-electron aromatic ring-current.

Funder

Division of Chemistry

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC03403K

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