Oxochlorin frameworks confining a β-hydroxyketone moiety-Reference-Cited by-同舟云学术

Oxochlorin frameworks confining a β-hydroxyketone moiety

Published:2024 Issue:31 Volume:53 Page:13142-13150
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chaudhri Nivedita¹²,Guberman-Pfeffer Matthew J.³^ORCID,Zeller Matthias⁴,Brückner Christian¹^ORCID

Affiliation:

1. Department of Chemistry, University of Connecticut, Storrs, CT 06269-3060, USA

2. Department of Chemistry, Guru Nanak Dev University Amritsar, Punjab-143005, India

3. Department of Chemistry and Biochemistry, Baylor University, One Bear Place #97348, Waco, Texas 76706, USA

4. Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907-2084, USA

Abstract

Despite the formal presence of an acac-like moiety, β-oxo-meso-OH-porphyrins do not bind 3d and 4d metal ions at their periphery. This is attributed to the loss of macrocycle aromaticity upon expression of an acac-like chelate.

Funder

Division of Chemistry

Baylor University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01386G

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