Disorder induced polymorphic transitions in the high hydrogen density compound Sr(BH4)2(NH3BH3)2-Reference-Cited by-同舟云学术

Disorder induced polymorphic transitions in the high hydrogen density compound Sr(BH4)2(NH3BH3)2

Published:2018 Issue:46 Volume:47 Page:16737-16746
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jørgensen Mathias¹²³⁴,Lee Young-Su⁵⁶⁷⁸^ORCID,Bjerring Morten¹²³⁴,Jepsen Lars H.⁹¹⁰⁴,Akbey Ümit¹²³⁴,Cho Young Whan⁵⁶⁷⁸,Jensen Torben R.¹²³⁴^ORCID

Affiliation:

1. Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry

2. University of Aarhus

3. DK-8000 Aarhus

4. Denmark

5. High Temperature Energy Materials Research Center

6. Korea Institute of Science and Technology

7. Seoul 02792

8. Republic of Korea

9. Danish Technological Institute

10. Aarhus

Abstract

The presence of two stable configurations of the ammonia borane molecule at elevated temperature induces a polymorphic phase transition to lower symmetry.

Funder

Danmarks Grundforskningsfond

Det Frie Forskningsråd

Carlsbergfondet

Korea Institute of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03654C

Reference42 articles.

1. Complex hydrides for hydrogen storage – new perspectives

2. Metal borohydrides and derivatives – synthesis, structure and properties

3. Boron–nitrogen based hydrides and reactive composites for hydrogen storage

4. Ammonia-Borane and Related Compounds as Dihydrogen Sources

5. Thermal decomposition of B–N–H compounds investigated by using combined thermoanalytical methods

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