Synthesis and characterisation of diphenylvinylphosphine-substituted osmium and ruthenium carbonyl clusters; crystal and molecular structures of [Os3(CO)11(Ph2PCHCH2)] and [Os3(µ-H)(CO)9(µ-Ph2PCHCH)]-Reference-Cited by-同舟云学术

Synthesis and characterisation of diphenylvinylphosphine-substituted osmium and ruthenium carbonyl clusters; crystal and molecular structures of [Os3(CO)11(Ph2PCHCH2)] and [Os3(µ-H)(CO)9(µ-Ph2PCHCH)]

Published:1996 Issue:19 Volume: Page:3825-3831
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Johnson Brian F. G.,Lewis Jack,Nordlander Ebbe,Raithby Paul R.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1996/DT/DT9960003825

Reference26 articles.

1. Complexes of Ph2PCHCH2 with PtX2 (X = Cl, Br, I or Me) or PdX2 (X = Cl, Br or I)

2. Generation of a bridging ethenyl ligand at a di-iron centre via carbonphosphorus bond cleavage

3. Reaction of diphenyl(vinyl)phosphine with carbonyls [M3(CO)12](M = Ru or Os); oxidative addition at [Ru3(CO)12]. Spectroscopic characterization and crystal structure of [Ru3(µ-H)(CO)8(Ph2PCHCH2)(µ3-Ph2PCHCH)]

4. Transformations of a µ2-vinyl ligand at a dimanganese centre and the flexibility of µ2-acyl lignads; X-ray crystal structures of [(Ph2P)2N][Mn2(µ2-H){µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6], [Mn2{µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6(CNBut)2], and [Mn2{σ : η3-P(Ph)2CH : CH2}(CO)7(PEt3)]

5. The reaction of [Mn2{µ-σ:η2-C(R)CHR}(µ-PPh2)(CO)7](R = H or Ph) with nucleophiles: X-ray crystal structures of [N(PPh3)2][Mn2(µ-H){µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6], [Mn2{PPh2C(Ph)CHPh}(CO)9], [Mn2(µ-PPh2CHCH2)(CO)8], [Mn2{µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)2], [Mn2{µ-σ:η2-C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)], and [Mn(µ-PPh2CHCH2)(CO)7(PEt3)]

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5. Triosmium Clusters on a Support: Determination of Structure by X-ray Absorption Spectroscopy and High-Resolution Microscopy;Chemistry - A European Journal;2010-11-23