The reaction of [Mn2{µ-σ:η2-C(R)CHR}(µ-PPh2)(CO)7](R = H or Ph) with nucleophiles: X-ray crystal structures of [N(PPh3)2][Mn2(µ-H){µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6], [Mn2{PPh2C(Ph)CHPh}(CO)9], [Mn2(µ-PPh2CHCH2)(CO)8], [Mn2{µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)2], [Mn2{µ-σ:η2-C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)], and [Mn(µ-PPh2CHCH2)(CO)7(PEt3)]-Reference-Cited by-同舟云学术

The reaction of [Mn2{µ-σ:η2-C(R)CHR}(µ-PPh2)(CO)7](R = H or Ph) with nucleophiles: X-ray crystal structures of [N(PPh3)2][Mn2(µ-H){µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6], [Mn2{PPh2C(Ph)CHPh}(CO)9], [Mn2(µ-PPh2CHCH2)(CO)8], [Mn2{µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)2], [Mn2{µ-σ:η2-C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)], and [Mn(µ-PPh2CHCH2)(CO)7(PEt3)]

Published:1987 Issue:11 Volume: Page:2669-2682
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Henrick Kim,McPartlin Mary,Iggo Jonathan A.,Kemball Alan C.,Mays Martin J.,Raithby Paul R.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1987/DT/DT9870002669

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