Covalent conjugation of a ‘hydroxide-philic’ functional group achieving ‘hydroxide-phobic’ TEMPO with superior stability in all-organic aqueous redox flow batteries

Author:

Seo Noh-Uk12,Kim Kyungmi13ORCID,Yeo Jeongmin4,Kwak Seung Jae5,Kim YongJoo6,Kim Hyemi3,Kim Mi Song3,Choi Jeongi3,Jung Yoon Seok2ORCID,Chae Junghyun3,Chang Jinho47ORCID,Yang Jung Hoon1ORCID

Affiliation:

1. Korea Institute of Energy Research (KIER), Daejeon 34129, Republic of Korea

2. Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Republic of Korea

3. Department of Chemistry, Sungshin Women's University, Seoul 01133, Republic of Korea

4. Department of Chemistry and Research Institute for Convergence of Basic Science, Hanyang University, Seoul 04763, Republic of Korea

5. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Seoul 08826, Republic of Korea

6. School of Advanced Materials Engineering, Kookmin University, Seoul 02707, Republic of Korea

7. Department of HY-KIST Bio-convergence, Hanyang University, Seoul 04763, Republic of Korea

Abstract

A hydroxide-philic functional group to a TEMPO is the key to mitigating chemical degradation during charge/discharge, which hinders OH-access to oxoammonium sites in the intramolecular regime, leading to a stable aqueous organic redox flow battery.

Funder

Samsung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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