Formation of the first heterobimetallic phosphido-bridged σ–π-acetylide complex [(C5H5)2Ti(µ–σ,η2-CCPh)(µ-PPh2)Ni(PPh3)] by cleavage of the central C–C single bond in PhCC–CCSiMe3and of the P–C bond in Ph3P, and coupling of the fragments to PhCCSiMe3
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1995/C3/C39950001753
Reference10 articles.
1. Die bildung von [Cp2Ti(CCSiMe3)]2 aus titanocen und 1,4-Bis(trimethylsilyl)-1,3-butadiin
2. Reaction of Disubstituted 1,3-Butadiynes R1C.tplbond.CC.tplbond.CR2 with Zirconocene Complexes: Cleavage of the Central C-C Single Bond to form Symmetrically and Unsymmetrically Doubly Acetylide-Bridged Metallocene Complexes
3. Heterobimetallic .sigma.,.pi.-Acetylide-Bridged Complexes from Disubstituted 1,3-Butadiynes
4. σ,π-acetylido complexes via P-C bond cleavage of phosphinoacetylenes: X-ray structure of Fe2(CO)6(C≡CPh)(PPh2)
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