Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(i) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt

Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(i) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt–Pt)

Published:2020 Issue:20 Volume:49 Page:6776-6789
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Todisco Stefano¹²³⁴⁵,Latronico Mario¹²³⁴⁵^ORCID,Gallo Vito¹²³⁴⁵,Re Nazzareno⁶⁷⁸,Marrone Alessandro⁶⁷⁸^ORCID,Tolbatov Iogann⁶⁷⁸^ORCID,Mastrorilli Piero¹²³⁴⁵^ORCID

Affiliation:

1. Dipartimento di Ingegneria Civile

2. Ambientale

3. del Territorio

4. Edile e di Chimica (DICATECh)

5. Politecnico di Bari

6. Dipartimento di Farmacia

7. Università di Chieti

8. Italy

Abstract

Double addition of phenylacetylene onto the Pt(i)–Pt(i) complex [(PHCy₂)Pt(μ-PCy₂){κ²P,O-μ-P(O)Cy₂}Pt(PHCy₂)] (Pt–Pt) affords the η¹-alkenyl-μ,η¹:η²-alkynyl complex [(η¹-trans-(Ph)HCCH)(PHCy₂)Pt(μ-PCy₂)(μ,η¹:η²-PhCC)Pt{κP-P(O)Cy₂}(PHCy₂)].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00923G

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