Extension and functionalization of an encapsulating macrobicyclic ligand using palladium-catalyzed Suzuki–Miyaura and Sonogashira reactions of iron(ii) dihalogenoclathrochelates with inherent halogen substituents

Author:

Denisenko Irina N.123,Varzatskii Oleg A.123ORCID,Selin Roman A.12345,Belov Alexander S.678ORCID,Lebed Ekaterina G.678,Vologzhanina Anna V.678ORCID,Zubavichus Yan V.910118ORCID,Voloshin Yan Z.678127ORCID

Affiliation:

1. Vernadskii Institute of General and Inorganic Chemistry NASU

2. 03142 Kiev

3. Ukraine

4. PBMR Labs Ukraine

5. 02094 Kiev

6. Nesmeyanov Institute of Organoelement Compounds RAS

7. 119991 Moscow

8. Russia

9. Kurchatov Complex for Synchrotron and Neutron Investigations

10. National Research Centre Kurchatov Institute

11. 123182 Moscow

12. Kurnakov Institute of General and Inorganic Chemistry RAS

Abstract

A new approach for performing Suzuki and Sonogashira reactions of iron(ii) dihalogenoclathrochelates, optimizing their reaction conditions, is elaborated.

Funder

Russian Science Foundation

Russian Foundation for Basic Research

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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