Combined spectroscopic studies on post-functionalized Au25 cluster as an ATR-FTIR sensor for cations-Reference-Cited by-同舟云学术

Combined spectroscopic studies on post-functionalized Au25 cluster as an ATR-FTIR sensor for cations

Published:2021 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Baghdasaryan Ani¹²³⁴^ORCID,Brun Elodie⁵²³⁴^ORCID,Wang Yuming¹²³⁴^ORCID,Salassa Giovanni¹²³⁴^ORCID,Lacour Jérôme⁵²³⁴^ORCID,Bürgi Thomas¹²³⁴^ORCID

Affiliation:

1. Department of Physical Chemistry

2. University of Geneva

3. 1211 Geneva 4

4. Switzerland

5. Department of Organic Chemistry

Abstract

Using ligand exchange reactions an atomically precise gold cluster was functionalized with a di-thiolated crown ether. Using in situ infrared spectroscopy films of the resulting composite were shown to incorporate metal cations.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Université de Genève

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01654G

Reference55 articles.

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3. Ligand Exchange Reactions on Au38 and Au40 Clusters: A Combined Circular Dichroism and Mass Spectrometry Study

4. In Situ Reaction Monitoring Reveals a Diastereoselective Ligand Exchange Reaction between the Intrinsically Chiral Au38(SR)24 and Chiral Thiols

5. Structural and Theoretical Basis for Ligand Exchange on Thiolate Monolayer Protected Gold Nanoclusters

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