Circularly polarized luminescence from Tb(iii) interacting with chiral polyether macrocycles

Author:

Homberg Alexandre1,Navazio Federica12,Le Tellier Antoine1,Zinna Francesco3ORCID,Fürstenberg Alexandre45ORCID,Besnard Céline6ORCID,Di Bari Lorenzo3ORCID,Lacour Jérôme1ORCID

Affiliation:

1. Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland

2. School of Science and Technology, Chemistry Division, University of Camerino, via S. Agostino n. 1, 62032 Camerino, Italy

3. Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Moruzzi 13, 56124 Pisa, Italy

4. Department of Inorganic and Analytical Chemistry, University of Geneva, 1211 Geneva, Switzerland

5. Department of Physical Chemistry, University of Geneva, 1211 Geneva, Switzerland

6. Laboratory of Crystallography, University of Geneva, Quai Ernest Ansermet 24, 1211 Geneva 4, Switzerland

Abstract

Chiral amide-based bis-pyridine polyether macrocycles interact with lanthanides. In the case of luminescent Tb(iii), the host-guest interaction can be observed by the ligand-centered ECD and by Tb-centered CPL.

Funder

Université de Genève

FP7 People: Marie-Curie Actions

Università degli Studi di Camerino

Università di Pisa

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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