Structure and photochemistry of di-<i>tert</i>-butyldiphosphatetrahedrane-Reference-Cited by-同舟云学术

Structure and photochemistry of di-tert-butyldiphosphatetrahedrane

Published:2024 Issue:15 Volume:15 Page:5596-5603
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hierlmeier Gabriele¹^ORCID,Kutta Roger Jan²^ORCID,Coburger Peter¹^ORCID,Stammler Hans-Georg³^ORCID,Schwabedissen Jan³,Mitzel Norbert W.³^ORCID,Dimitrova Maria⁴⁵^ORCID,Berger Raphael J. F.⁵^ORCID,Nuernberger Patrick²^ORCID,Wolf Robert¹^ORCID

Affiliation:

1. Universität Regensburg, Institut für Anorganische Chemie, 93040 Regensburg, Germany

2. Universität Regensburg, Institut für Physikalische und Theoretische Chemie, 93040 Regensburg, Germany

3. Universität Bielefeld, Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstraße 25, 33615 Bielefeld, Germany

4. Department of Chemistry, University of Helsinki, Faculty of Science, FI-00014 Helsinki, Finland

5. Paris Lodron Universität Salzburg, Chemie und Physik der Materialien, 5020 Salzburg, Austria

Abstract

Crystallographic and quantum chemical studies reveal a close relationship of (tBuCP)2 with P4. Photochemical transformations proceed via the 1,2-diphosphacyclobutadiene isomer, which dimerises to give (tBuCP)4 in the absence of a trap.

Funder

Fonds der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00936C

Reference44 articles.

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