Metallofullerene photoswitches driven by photoinduced fullerene-to-metal electron transfer

Author:

Zalibera Michal12345ORCID,Ziegs Frank678,Schiemenz Sandra678,Dubrovin Vasilii678ORCID,Lubitz Wolfgang598ORCID,Savitsky Anton5981011,Deng Shihu H. M.12131415,Wang Xue-Bin12131415ORCID,Avdoshenko Stanislav M.678ORCID,Popov Alexey A.678ORCID

Affiliation:

1. Institute of Physical Chemistry and Chemical Physics

2. Slovak University of Technology in Bratislava

3. 81237 Bratislava

4. Slovakia

5. Max Planck Institute for Chemical Energy Conversion

6. Leibniz Institute for Solid State and Materials Research

7. 01069 Dresden

8. Germany

9. Mülheim (Ruhr)

10. Faculty of Physics

11. Technical University Dortmund

12. Physical Sciences Division

13. Pacific Northwest National Laboratory

14. Richland

15. USA

Abstract

Photoexcitation mechanism of YxSc3−xN@C80 metallofullerenes is studied by variable-temperature photoluminescence, advanced EPR techniques, and DFT calculations, revealing photoinduced rotation of the endohedral cluster.

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Deutsche Forschungsgemeinschaft

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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