Hydrogen evolution reaction mediated by an all-sulfur trinuclear nickel complex-Reference-Cited by-同舟云学术

Hydrogen evolution reaction mediated by an all-sulfur trinuclear nickel complex

Published:2020 Issue:75 Volume:56 Page:11106-11109
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Pieri Cyril¹²³⁴⁵,Bhattacharjee Anirban⁶⁷⁸,Barrozo Alexandre¹²³⁴⁵^ORCID,Faure Bruno¹²³⁴⁵^ORCID,Giorgi Michel¹²³⁵⁹^ORCID,Fize Jennifer¹⁰²¹¹¹²¹³,Réglier Marius¹²³⁴⁵,Field Martin¹⁰²¹¹¹²¹³,Orio Maylis¹²³⁴⁵^ORCID,Artero Vincent¹⁰²¹¹¹²¹³^ORCID,Hardré Renaud¹²³⁴⁵

Affiliation:

1. Aix Marseille Univ

2. CNRS

3. Centrale Marseille

4. iSm2

5. Marseille

6. Socivolta Inc.

7. Montreal

8. Canada

9. France

10. Univ. Grenoble Alpes

11. CEA

12. IRIG

13. Laboratoire de Chimie et Biologie des Métaux

Abstract

A trinuclear nickel complex with S-based ligands is reported as a bio-inspired model of the [NiFe] hydrogenases' active site. DFT calculations indicate that thiolate and thioether functions are involved as proton relays in the H₂ evolution mechanism.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC04174B

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