<i>E</i>-Selective semi-hydrogenation of alkynes <i>via</i> a sulfur-radical mediation over cyclodextrin-modified nickel nanocatalyst-Reference-Cited by-同舟云学术

E-Selective semi-hydrogenation of alkynes via a sulfur-radical mediation over cyclodextrin-modified nickel nanocatalyst

Published:2023 Issue:6 Volume:13 Page:1718-1724
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Su Yatao¹,Wang Xiu¹,Lin Qianwen¹,Shen Qi¹,Xu Shuangwen¹,Fang Liping¹,Wen Xin¹^ORCID

Affiliation:

1. Key Laboratory of Chemical Biology of Hebei Province, College of Chemistry and Materials Science, Hebei University, Baoding 071002, China

Abstract

An efficient cyclodextrin-modified Ni catalyst was developed for E-selective semi-hydrogenation of alkynes that takes into account for the highly active Hδ− and Hδ+, in situ formed Ni nanoparticles, and the host–guest interaction.

Funder

National Natural Science Foundation of China

Hebei University

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D2CY01984A

Reference42 articles.

1. Zeolite-Encaged Isolated Platinum Ions Enable Heterolytic Dihydrogen Activation and Selective Hydrogenations

2. Enabling Semihydrogenation of Alkynes to Alkenes by Using a Calcium Palladium Complex Hydride

3. Influence of Pd deposition pH value on the performance of Pd-CuO/SiO2 catalyst for semi-hydrogenation of 2-methyl-3-butyn-2-ol (MBY)

4. Are Alkyne Reductions Chemo-, Regio-, and Stereoselective Enough To Provide Pure (Z)-Olefins in Polyfunctionalized Bioactive Molecules?

5. Advances in chemoselective and/or stereoselective semihydrogenation of alkynes

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