Optimized iminium-catalysed 1,4-reductions inside the resorcinarene capsule: achieving >90% ee with proline as catalyst
Author:
Affiliation:
1. Department of Chemistry
2. University of Basel
3. 4058 Basel
4. Switzerland
5. Department of Biosystems Science and Engineering
Abstract
A supramolecular container enables highly enantioselective iminium chemistry using simple proline as the chiral source.
Funder
H2020 European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA04333A
Reference38 articles.
1. A chiral spherical molecular assembly held together by 60 hydrogen bonds
2. Spontaneous Formation of Hexameric Resorcinarene Capsule in Chloroform Solution as Detected by Diffusion NMR
3. Recent advances in hydrogen-bonded hexameric encapsulation complexes
4. Reversible encapsulation by self-assembling resorcinarene subunits
5. Discrimination of Guests Encapsulation in Large Hexameric Molecular Capsules in Solution: Pyrogallol[4]arene versus Resorcin[4]arene Capsules
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