A macrocycle-based new organometallic nano-vessel towards sustainable C2-selective arylation of free indole in water

Author:

Mandal Subham1,Sarkar Piyali2,Ghosh Pradyut1ORCID

Affiliation:

1. School of Chemical Sciences, Indian Association for the Cultivation of Science, 2A & 2B Raja S.C. Mullick Road, Kolkata 700032, India

2. Institute of Health Sciences, Presidency University, Second Campus, Plot No. DG/02/02, Premises No. 14-0358, Action Area-ID, New Town, Kolkata 700156, West Bengal, India

Abstract

C2-selectivity of unsubstituted indole over facile C3-substitution is attempted by utilizing the π-cavity of a nano-vessel made up of a palladium complex of an amino-ether heteroditopic macrocycle.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

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