Insight into the chemoselective aromatic vs. side-chain hydroxylation of alkylaromatics with H2O2 catalyzed by a non-heme imine-based iron complex-Reference-Cited by-同舟云学术

Insight into the chemoselective aromatic vs. side-chain hydroxylation of alkylaromatics with H2O2 catalyzed by a non-heme imine-based iron complex

Published:2021 Issue:1 Volume:11 Page:171-178
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Ticconi Barbara¹²³⁴⁵,Capocasa Giorgio¹²³⁴⁵,Cerrato Andrea¹²³⁴⁵,Di Stefano Stefano¹²³⁴⁵^ORCID,Lapi Andrea¹²³⁴⁵^ORCID,Marincioni Beatrice¹²³⁴⁵,Olivo Giorgio⁶⁷⁸⁹^ORCID,Lanzalunga Osvaldo¹²³⁴⁵^ORCID

Affiliation:

1. Dipartimento di Chimica

2. Università degli Studi di Roma “La Sapienza” and

3. Istituto CNR per i Sistemi Biologici (ISB-CNR)

4. Sezione Meccanismi di Reazione, c/o Dipartimento di Chimica

5. Università degli Studi di Roma “La Sapienza”

6. Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química

7. Universitat de Girona

8. 17003 Girona

9. Spain

Abstract

Side-chain/ring oxygenated product ratio increases upon decreasing the benzylic bond dissociation energy in the oxidation of alkylaromatics with H₂O₂ catalyzed by an imine-based iron complex.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Sapienza Università di Roma

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY01868F

Reference75 articles.

1. One-Step Selective Hydroxylation of Benzene to Phenol

2. Accessing Drug Metabolites via Transition-Metal Catalyzed C−H Oxidation: The Liver as Synthetic Inspiration