Affiliation:
1. Dipartimento di Chimica Università di Roma “La Sapienza” P.le A. Moro, 5 00185 Rome Italy
2. CIRCC Interuniversity Consortium Chemical Reactivity and Catalysis Via Celso Ulpiani 27 70126 Bari Italy
3. Dipartimento di Scienze Chimiche and CIRCC Università degli Studi di Padova via Marzolo, 1 I-35131 Padua Italy
Abstract
AbstractIn this perspective, two different classes of multidentate ligands (aminotriphenolate and dipyridinimine) and the corresponding metal (Ti, V, Mo, W, Fe) complexes are described. These catalysts can activate efficiently the environmental benign H2O2 oxidant, promoting a wide variety of oxidative processes (sulfoxidations, N‐oxidations, epoxidations, haloperoxidation, alcohol oxidation, hydroxylation).