Terpenoid-derived conjugated dienes with exo-methylene and a 6-membered ring: high cationic reactivity, regioselective living cationic polymerization, and random and block copolymerization with vinyl ethers

Author:

Nishida Takenori12345,Satoh Kotaro12345ORCID,Tamura Masazumi67895ORCID,Li Yingai101112135,Tomishige Keiichi101112135ORCID,Caillol Sylvain1415161718ORCID,Ladmiral Vincent1415161718ORCID,Vayer Marylène1920212223,Mahut Frédéric1920212223,Sinturel Christophe1920212223ORCID,Kamigaito Masami12345ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry

2. Graduate School of Engineering

3. Nagoya University

4. Nagoya 464-8603

5. Japan

6. Research Center for Artificial Photosynthesis

7. Advanced Research Institute for Natural Science and Technology

8. Osaka City University

9. Osaka

10. Department of Applied Chemistry

11. School of Engineering

12. Tohoku University

13. Sendai 980-8579

14. ICGM

15. Univ Montpellier

16. CNRS

17. ENSCM

18. Montpellier

19. Interfaces

20. Confinement

21. Matériaux et Nanostructures (ICMN)

22. UMR 7374

23. CNRS-Université d'Orléans

Abstract

Biobased exo-methylene-conjugated dienes underwent regioselective living cationic polymerization to result in well-defined homo- and copolymers with good thermal properties.

Funder

Japan Society for the Promotion of Science

Centre National de la Recherche Scientifique

New Energy and Industrial Technology Development Organization

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference47 articles.

1. J. D. Connolly and R. A.Hill , Dictionary of terpenoids , Chapman & Hall , London , 1991

2. R. Breitmaier , Terpenes: flavors, fragrances, pharmaca, pheromones , Wiley-VCH , Weinheim , 2006

3. Handbook of essential oils: science, technology, and applications , ed. K. H. C. Başer and G. Buchbouer , CRC Press , Boca Baton , 2016

4. W. F. Erman , Chemistry of the monoterpenes: an encyclopedia handbook , Marcel Dekker, Inc , New York , 1985

5. Controlled Polymerization of Next-Generation Renewable Monomers and Beyond

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