Water oxidation catalysis – role of redox and structural dynamics in biological photosynthesis and inorganic manganese oxides

Author:

Zaharieva I.1234,González-Flores D.1234,Asfari B.1234,Pasquini C.1234,Mohammadi M. R.1234,Klingan K.1234,Zizak I.5674,Loos S.1234,Chernev P.1234,Dau H.1234

Affiliation:

1. Freie Universität Berlin

2. Fachbereich Physik

3. 14195 Berlin

4. Germany

5. Helmholtz-Zentrum-Berlin

6. Institute for Nanometre Optics and Technology

7. 12489 Berlin

Abstract

Water oxidation is pivotal in biological photosynthesis, where it is catalyzed by a protein-bound metal complex with a Mn4Ca-oxide core; related synthetic catalysts may become key components in non-fossil fuel technologies.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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