Manganese dissolution in alkaline medium with and without concurrent oxygen evolution in LiMn2O4

Author:

Bisen Omeshwari Yadorao12ORCID,Baumung Max12,Tatzel Michael3,Volkert Cynthia A.1,Risch Marcel12ORCID

Affiliation:

1. Institute of Materials Physics, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany

2. Nachwuchsgruppe Gestaltung des Sauerstoffentwicklungsmechanismus, Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

3. Department of Sedimentology & Environmental Geology, University of Göttingen, Goldschmidtstr. 3, 37077 Göttingen, Germany

Abstract

Manganese oxides such as LiMn2O4 exhibit two distinct Mn dissolution processes; one independent of oxygen evolution and the other associated with it. Less Mn4+ before the onset of the OER lowers the Mn dissolution rate.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy (miscellaneous),Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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