Substituent-controlled selective synthesis of 1,2-diketones and internal alkynes from terminal alkynes and arylboronic acids <i>via</i> α-stilbene radicals obtained from heteroleptic Cu(<scp>i</scp>) complexes under visible light-Reference-Cited by-同舟云学术

Substituent-controlled selective synthesis of 1,2-diketones and internal alkynes from terminal alkynes and arylboronic acids via α-stilbene radicals obtained from heteroleptic Cu(i) complexes under visible light

Published:2022 Issue:22 Volume:24 Page:8685-8690
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Neerathilingam Nalladhambi¹,Prasanth Kesavan¹,Anandhan Ramasamy¹^ORCID

Affiliation:

1. Department of Organic chemistry, University of Madras, Chennai 600025, India

Abstract

Herein, we report a substituent-controlled synthesis of 1,2-diketones and internal alkynes from terminal alkynes and arylboronic acids via α-stilbene radicals obtained from heteroleptic Cu(i) complexes under visible-light irradiation.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC03011J

Reference46 articles.

1. Prenylated flavonoids from the aerial parts of Dorstenia mannii

2. A benzil and isoflavone derivatives from Derris scandens Benth.

3. Catalytic Asymmetric Intermolecular Stetter Reaction of Glyoxamides with Alkylidenemalonates

4. Planarity and Constraint of the Carbonyl Groups in 1,2-Diones Are Determinants for Selective Inhibition of Human Carboxylesterase 1

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Mimicking Ozonolysis via Mechanochemistry: Internal Alkynes to 1,2‐Diketones using H₅IO₆;Chemistry – A European Journal;2024-05-23

2. Modern photo- and electrochemical approaches to aryl radical generation;Organic Chemistry Frontiers;2024

3. Metal-free oxidative coupling of aryl acetylene with elemental sulphur and amines: facile access to α-ketothioamides;Organic & Biomolecular Chemistry;2024