Impacts of extending the π-conjugation of the 2,2′-biquinoline ligand on the photophysics and reverse saturable absorption of heteroleptic cationic iridium(iii) complexes-Reference-Cited by-同舟云学术

Impacts of extending the π-conjugation of the 2,2′-biquinoline ligand on the photophysics and reverse saturable absorption of heteroleptic cationic iridium(iii) complexes

Published:2021 Issue:44 Volume:9 Page:15932-15941
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Lu Taotao¹,Lu Cuifen¹²^ORCID,Cui Peng¹³⁴,Kilina Svetlana¹,Sun Wenfang¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, North Dakota State University, Fargo, ND 58108-6050, USA

2. Hubei Collaborative Innovation Center for Advanced Organochemical Materials & Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan, 430062, P. R. China

3. Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, P. R. China

4. Materials and Nanotechnology Program, North Dakota State University, Fargo, ND 58108-6050, USA

Abstract

Extending the π-conjugation of the 2,2′-biquinoline ligand in Ir(iii) complexes via 7-benzothiazolylfluoren-2-yl substitution increased the triplet excited-state lifetime, leading to broad excited-state absorption at 480–800 nm and strong RSA at 532 nm.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TC/D1TC03601G

Reference76 articles.

1. Recent progress in metal–organic complexes for optoelectronic applications

2. A family of luminescent coordination compounds: iridium(iii) polyimine complexes

3. Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes