Mechanism and selectivity of photocatalyzed CO<sub>2</sub> reduction by a function-integrated Ru catalyst-Reference-Cited by-同舟云学术

Mechanism and selectivity of photocatalyzed CO₂ reduction by a function-integrated Ru catalyst

Published:2022 Issue:9 Volume:51 Page:3747-3759
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Ya-Qiong¹,Li Ying-Ying¹,Maseras Feliu²^ORCID,Liao Rong-Zhen¹^ORCID

Affiliation:

1. Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, Hubei Key Laboratory of Materials Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

2. Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Avgda. Països Catalans, 16, 43007 Tarragona, Catalonia, Spain

Abstract

Density functional calculations were performed to elucidate the reaction mechanism and understand the origin of selectivity of photocatalyzed CO2 reduction by a functional-integrated Ru(ii) complex, [RuII-(tpy)(pqn)(MeCN)]2+.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03825G

Reference98 articles.

1. The Holy Grail: Chemistry Enabling an Economically Viable CO2 Capture, Utilization, and Storage Strategy

2. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation