Regioselective addition of Grignard reagents to tosylazafulleroid and derivatization to 1,2-disubstituted [60]fullerene-Reference-Cited by-同舟云学术

Regioselective addition of Grignard reagents to tosylazafulleroid and derivatization to 1,2-disubstituted [60]fullerene

Published:2016 Issue:29 Volume:14 Page:7103-7108
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ikuma Naohiko¹²³⁴⁵,Nakagawa Koji¹²³⁴⁵,Kokubo Ken¹²³⁴⁵,Oshima Takumi¹²³⁴⁵

Affiliation:

1. Division of Applied Chemistry

2. Graduate School of Engineering

3. Osaka University

4. Suita

5. Japan

Abstract

Grignard reaction with tosylazafulleroid selectively gave tosyl aminylfullerene with the relatively rare 1,2-configuration, via [5,6] ring-closure and CN-bond scission.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00869K

Reference65 articles.

1. Fullerene Chemistry in Three Dimensions: Isolation of Seven Regioisomeric Bisadducts and Chiral Trisadducts of C60 and Di(ethoxycarbonyl)methylene

2. Regiochemistry of Twofold Additions to [6,6] Bonds in C60: Influence of the Addend-Independent Cage Distortion in 1,2-Monoadducts

3. Biscycloaddition to [60]Fullerene: Regioselectivity and Its Control with Templates

4. Self-Assembling Fullerenes for Improved Bulk-Heterojunction Photovoltaic Devices

5. Penta(organo)[60]fullerenes as acceptors for organic photovoltaic cells

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