Synthesis and comparison of iso-structural f-block metal complexes (Ce, U, Np, Pu) featuring <i>η</i><sup>6</sup>-arene interactions-Reference-Cited by-同舟云学术

Synthesis and comparison of iso-structural f-block metal complexes (Ce, U, Np, Pu) featuring η⁶-arene interactions

Published:2023 Issue:27 Volume:14 Page:7438-7446
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Murillo Jesse¹²,Goodwin Conrad A. P.²^ORCID,Stevens Lauren²³,Fortier Skye¹^ORCID,Gaunt Andrew J.²^ORCID,Scott Brian L.³^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Texas at El Paso, El Paso, Texas 79968, USA

2. Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

3. Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

Abstract

Reaction of a terphenyl bis(anilide) ligand with trivalent halide precursors of Ce and early actinides yield both neutral and “-ate” complexes. These molecules afford comparative insight into f-block metal–arene bonding.

Funder

Los Alamos National Laboratory

Laboratory Directed Research and Development

Welch Foundation

University of Texas at El Paso

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02194G

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