What is the nature of the uranium(<scp>iii</scp>)–arene bond?-Reference-Cited by-同舟云学术

What is the nature of the uranium(iii)–arene bond?

Published:2024 Issue:5 Volume:15 Page:1810-1819
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chowdhury Sabyasachi Roy¹^ORCID,Goodwin Conrad A. P.²³^ORCID,Vlaisavljevich Bess¹^ORCID

Affiliation:

1. University of South Dakota, 414 E Clark St., Vermillion, SD, 57069, USA

2. Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK

3. Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK

Abstract

Complexes of the form [U(η6-arene)(BH4)3] where arene = C6H6; C6H5Me; C6H3-1,3,5-R3 (R = Et, iPr, tBu, Ph); C6Me6; and triphenylene (C6H4)3 were investigated towards an understanding of the nature of the uranium–arene interaction.

Funder

Basic Energy Sciences

Royal Society

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC04715F

Reference66 articles.

1. The Renaissance of Non-Aqueous Uranium Chemistry

2. From Chemical Curiosities and Trophy Molecules to Uranium-Based Catalysis: Developments for Uranium Catalysis as a New Facet in Molecular Uranium Chemistry

3. Uranium(III) Complexes with Bulky Aryloxide Ligands Featuring Metal–Arene Interactions and Their Reactivity Toward Nitrous Oxide

4. Uranium-mediated electrocatalytic dihydrogen production from water

5. Medicinal Organometallic Chemistry: Designing Metal Arene Complexes as Anticancer Agents

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