Palladium-catalyzed asymmetric allylic amination: enantioselective synthesis of chiral α-methylene substituted β-aminophosphonates-Reference-Cited by-同舟云学术

Palladium-catalyzed asymmetric allylic amination: enantioselective synthesis of chiral α-methylene substituted β-aminophosphonates

Published:2017 Issue:2 Volume:4 Page:271-276
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Xubin¹²³⁴⁵,Wang Xiaoming¹²³⁴⁵,Han Zhaobin¹²³⁴⁵,Wang Zheng¹²³⁴⁵,Ding Kuiling¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. China

Abstract

Palladium catalyzed asymmetric allylic amination of 2-diethylphosphonate-substituted allylic acetates in the presence of SKP ligands afforded the corresponding chiral β-aminophosphonates in good yields, high regioselectivities, and excellent enantioselectivities.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00597G

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