TADDOL-based P,S-bidentate phosphoramidite ligands in palladium-catalyzed asymmetric allylic substitution

Author:

Gavrilov Konstantin N.1ORCID,Chuchelkin Ilya V.1ORCID,Firsin Ilya D.1ORCID,Trunina Valeria M.1,Gavrilov Vladislav K.1ORCID,Zheglov Sergey V.1,Fedorov Denis A.2,Tafeenko Victor A.3,Zamilatskov Ilya A.4,Zimarev Vladislav S.13,Goulioukina Nataliya S.134ORCID

Affiliation:

1. Department of Chemistry, Ryazan State University named for S. Yesenin, 46 Svoboda Street, 390000 Ryazan, Russian Federation

2. Department of General Physics, Moscow Institute of Physics and Technology, Institutskii per. 9, 141700 Dolgoprudny, Moscow Region, Russian Federation

3. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, GSP-1, 119991 Moscow, Russian Federation

4. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prospekt 31/4, 119071, Moscow, Russian Federation

Abstract

Phosphoramidite-thioethers with a TADDOL backbone as brand new P,S-bidentate stereoselectors for Pd-mediated asymmetric allylation.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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