Electrochemical synthesis of copper(i) acetylides via simultaneous copper ion and catalytic base electrogeneration for use in click chemistry-Reference-Cited by-同舟云学术

Electrochemical synthesis of copper(i) acetylides via simultaneous copper ion and catalytic base electrogeneration for use in click chemistry

Published:2019 Issue:50 Volume:9 Page:29300-29304
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Seavill Peter W.¹²³⁴^ORCID,Holt Katherine B.¹²³⁴^ORCID,Wilden Jonathan D.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University College London

3. London

4. UK

Abstract

We report an efficient and sustainable electrochemical synthesis of copper(i) acetylides using simultaneous copper oxidation and Hofmann elimination of quaternary ammonium salts.

Funder

University College London

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA06782E

Reference33 articles.

1. Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper

2. Electrochemical preparation and applications of copper(i) acetylides: a demonstration of how electrochemistry can be used to facilitate sustainability in homogeneous catalysis

3. Tandem Reaction of 1-Copper(I) Alkynes for the Synthesis of 1,4,5-Trisubstituted 5-Chloro-1,2,3-triazoles

4. The Substitution of Aryl Iodides with Cuprous Acetylides. A Synthesis of Tolanes and Heterocyclics1

5. Triflimide Activation of a Chiral Oxazaborolidine Leads to a More General Catalytic System for Enantioselective Diels−Alder Addition

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