Replacing a stoichiometric silver oxidant with air: ligated Pd(ii)-catalysis to β-aryl carbonyl derivatives with improved chemoselectivity-Reference-Cited by-同舟云学术

Replacing a stoichiometric silver oxidant with air: ligated Pd(ii)-catalysis to β-aryl carbonyl derivatives with improved chemoselectivity

Published:2014 Issue:5 Volume:16 Page:2788-2797
ISSN:1463-9262
Container-title:Green Chem.
language:en
Short-container-title:Green Chem.

Author:

Vellakkaran Mari¹²³,Andappan Murugaiah M. S.⁴⁵,Kommu Nagaiah¹²³

Affiliation:

1. Organic and Biomolecular Chemistry Division

2. CSIR-Indian Institute of Chemical Technology

3. Hyderabad, India

4. Syngene

5. Bengaluru, India

Abstract

Air was employed as a green reoxidant of Pd(0), replacing stoichiometric and toxic silver salt, in the chelation-controlled Pd(ii)-modulated arylative enolization of prop-2-en-1-ols to acquire synthetically-important β-aryl carbonyl derivatives.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/GC/C3GC42504E

Reference94 articles.

1. An efficient palladium(II) catalyst for oxidative Heck-type reaction under base-free conditions

2. Ligand-free Palladium-Catalyzed Mizoroki-Heck-type Reaction of Arylboronic Acids and Alkenes Using Silver Cation

3. Oxidative Heck Arylation for the Stereoselective Synthesis of Tetrasubstituted Olefins Using Nitroxides as Oxidants

4. Synthetic approach to flavanones and flavones via ligand-free palladium(ii)-catalyzed conjugate addition of arylboronic acids to chromones

5. The ligand and base-free Pd-catalyzed oxidative Heck reaction of arylboronic acids and olefins

Cited by 30 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Rhodium‐Catalysed Selective C−H Allylation of 1H‐Indazoles with Vinylethylene Carbonate: Easily Introducing Allylic Alcohol;European Journal of Organic Chemistry;2023-09-25

2. Palladium-Catalyzed Multicomponent Cascade Reaction of 3-Hydroxypropionitrile: Synthesis of Substituted Dihydrochalcones;The Journal of Organic Chemistry;2023-06-09

3. Examining the Scope of Deriving β-Aryl Enones from Enol Silanes as Ketone Equivalents via Pd(II)-Mediated Sequential Dehydrosilylation and Arylation;The Journal of Organic Chemistry;2023-05-16

4. Synthesis of vinyl-substituted alcohols using acetylene as a C2 building block;Chemical Science;2023

5. Palladium-Catalyzed Oxidative Nonclassical Heck Reaction of Arylhydrazines with Allylic Alcohols via C–N Bond Cleavage: Access to β-Arylated Carbonyl Compounds;The Journal of Organic Chemistry;2022-07-25