Operandomonitoring of mechanisms and deactivation of molecular catalysts

Author:

Köhnke Katrin1ORCID,Wessel Niklas1,Esteban Jesús12ORCID,Jin Jing1ORCID,Vorholt Andreas J.1ORCID,Leitner Walter13ORCID

Affiliation:

1. Max-Planck-Institut für Chemische Energiekonversion, Stiftstraße 34-36, 45740 Mülheim an der Ruhr, Germany

2. Department of Chemical Engineering and Analytical Science, School of Engineering, The University of Manchester, Manchester M13 9PL, UK

3. Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

Abstract

The review presents spectroscopic and mathematical tools to performoperandoinvestigations of mechanisms and deactivation pathways in homogeneous catalysis. Their potential is shown in two case studies, hydroformylation and asymmetric hydrogenation.

Funder

Deutsche Forschungsgemeinschaft

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference160 articles.

1. P. C. J.Kamer , D.Vogt and J. W.Thybaut , Contemporary Catalysis: Science, Technology, and Applications , RSC Publishing , Cambridge , 2017

2. A.Behr and P.Neubert , Applied Homogeneous Catalysis , Wiley-VCH , Weinheim, Germany , 2012

3. Decomposition pathways of homogeneous catalysts

4. P. W. N. M.Van Leeuwen and J. C.Chadwick , Homogeneous Catalysts: Activity – Stability – Deactivation , Wiley-VCH , Weinheim , 2011

5. Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure

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