Unusual formation of a N-heterocyclic germylene via homolytic cleavage of a C

Unusual formation of a N-heterocyclic germylene via homolytic cleavage of a C–C bond

Published:2014 Issue:25 Volume:50 Page:3356-3358
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Li Yan¹²³⁴⁵,Mondal Kartik Chandra⁵⁶⁷,Stollberg Peter⁵⁶⁷,Zhu Hongping¹²³⁴,Roesky Herbert W.⁵⁶⁷,Herbst-Irmer Regine⁵⁶⁷,Stalke Dietmar⁵⁶⁷,Fliegl Heike⁸⁹¹⁰¹¹

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces

2. College of Chemistry and Chemical Engineering

3. Xiamen University

4. Xiamen, China

5. Institut für Anorganische Chemie

6. Georg-August-Universität

7. 37077-Göttingen, Germany

8. Department of Chemistry

9. Centre for Theoretical and Computational Chemistry

10. University of Oslo

11. 0315 Oslo, Norway

Abstract

A N-heterocyclic germylene has been synthesized via an unusual homolytic cleavage of a C–C bond under reductive conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC00251B

Reference33 articles.

1. N-heterocyclic germylenes and related compounds

2. Stable Heavier Carbene Analogues

3. N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands

4. Interstellar molecules: guides for new chemistry

5. Stable Cyclic Germanediyls(“Cyclogermylenes”): Synthesis, Structure, Metal Complexes, and Thermolyses

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