A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor-Reference-Cited by-同舟云学术

A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor

Published:2022 Issue:96 Volume:58 Page:13357-13360
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cui Jingjing¹²³,Weiser Jonas²³⁴^ORCID,Fantuzzi Felipe⁵^ORCID,Dietz Maximilian²³,Yatsenko Yelyzaveta²³,Häfner Andreas²³,Nees Samuel²³,Krummenacher Ivo²³,Zhang Mingtao⁶^ORCID,Hammond Kai²³,Roth Paula²³,Lu Wei²³,Dewhurst Rian D.²³^ORCID,Engels Bernd⁴^ORCID,Braunschweig Holger²³^ORCID

Affiliation:

1. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, P. R. China

2. Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

3. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

4. Institute for Physical and Theoretical Chemistry, Julius-Maximilians-Universität Würzburg, Emil-Fischer-Str. 42, 97074 Würzburg, Germany

5. School of Chemistry and Forensic Science, University of Kent, Park Wood Rd, Canterbury CT2 7NH, UK

6. A201, Centlab, College of Chemistry, Nankai University, Weijin Road, 94, DE 300071 Tianjin, P. R. China

Abstract

A bis(germylene) based on a naphthyridinediamine (NDI) is reported. Calculations on the [NDI-Ge2][Fe2(CO)6] complex revealed the six-electron donor behavior of NDI-Ge2, the first of its kind for bidentate ligands based on group 14 elements.

Funder

National Natural Science Foundation of China

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC05325J

Reference50 articles.

1. Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands

2. N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field

3. Where silylene–silicon centres matter in the activation of small molecules

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