Metallic vs. semiconducting properties of quasi-one-dimensional tantalum selenide van der Waals nanoribbons

Author:

Kargar Fariborz1ORCID,Krayev Andrey2ORCID,Wurch Michelle13,Ghafouri Yassamin4,Debnath Topojit5ORCID,Wickramaratne Darshana6ORCID,Salguero Tina T.4ORCID,Lake Roger K.5ORCID,Bartels Ludwig3,Balandin Alexander A.1ORCID

Affiliation:

1. Nano-Device Laboratory (NDL) and Phonon Optimized Engineered Materials (POEM) Center, Department of Electrical and Computer Engineering, University of California, Riverside, California 92521, USA

2. HORIBA Scientific, Novato, California, 94949, USA

3. Department of Chemistry and Material Science and Engineering Program, University of California, Riverside, California 92521, USA

4. Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA

5. Laboratory for Terahertz and Terascale Electronics, Department of Electrical and Computer Engineering, University of California, Riverside, California 92521, USA

6. Center for Computational Materials Science, U.S. Naval Research Laboratory, Washington, DC 20375, USA

Abstract

We studied the properties of TaSe3−δ quasi-1D nanoribbons using tip-enhanced Raman scattering (TERS), photoluminescence, and electrical transport measurements. The results show TaSe3−δ shifts from metallic to semiconductor at higher Se deficiencies.

Funder

National Science Foundation

Office of Naval Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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