Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer
Author:
Affiliation:
1. Department of Chemistry
2. University of Toronto
3. Toronto
4. Canada
5. Massachusetts Institute of Technology
6. Cambridge
7. USA
Abstract
Acyl(chloro)phosphines RC(O)P(Cl)(t-Bu) have been prepared by formal insertion of tert-butyl phosphinidene (t-Bu–P) from t-BuPA (A = C14H10 or anthracene) into the C–Cl bond of acyl chlorides.
Funder
Division of Chemistry
Natural Sciences and Engineering Research Council of Canada
University of Toronto
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC05657A
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